Statistika sobstvennykh elektrolitov (Russian Edition)

Statistika sobstvennykh elektrolitov (Russian Edition)

by V. Shikin, S. Nazin, Yu. Shikina

84 pages· 2014· ISBN 9783659515149
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Predlagaetsya sistematicheskoe tolkovanie ravnovesnykh i prosteyshikh transportnykh svoystv zhidkikh elektrolitov, normal'nykh i kriogennykh. V osnove rassmotreniya vvodimye fenomenologicheski mikrokharakteristiki otdel'nykh zaryazhennykh klasterov: ikh energii, zakony dispersii, effektivnye massy raznogo proiskhozhdeniya i t.p. Podrobno obsuzhdayutsya vozmozhnosti ekstragirovaniya etikh parametrov iz eksperimental'nykh dannykh, chto kriticheski vazhno dlya obosnovaniya samoy vozmozhnosti statisticheskogo rassmotreniya proiskhodyashchego. Otmechena glubokaya analogiya mezhdu statistikoy elektrolitov i tverdotel'nykh poluprovodnikov. V ramkakh statisticheskogo formalizma obsuzhdayutsya detali protsessa dissotsiatsii v zhidkikh provodyashchikh sredakh. Vvedeno ponyatie sobstvennykh i nesobstvennykh elektrolitov, dano estestvennoe ob"yasnenie proiskhozhdeniyu slabykh i sil'nykh elektrolitov, oboznacheny vozmozhnosti ucheta neideal'nosti kulonovski vzaimodeystvuyushchego ansamblya chastits. Demonstriruetsya vazhnaya rol' vneshnikh poley v formirovanii usloviy dlya nakhozhdeniya osnovnykh fenomenologicheskikh konstant teorii. Obrashchaetsya vnimanie na zametnoe uchastie vneshnikh poley v protsesse dissotsiatsii i formirovanii ravnovesnykh svoystv neodnorodnykh elektrolitov.

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